917839-23-7Relevant articles and documents
Stereocontrolled route to vicinal diamines by [3.3] sigmatropic rearrangement of allyl cyanate: Asymmetric synthesis of anti-(2R,3R)- and syn-(2R,3S)-2,3-diaminobutanoic acids
Ichikawa, Yoshiyasu,Egawa, Haruka,Ito, Takashi,Isobe, Minoru,Nakano, Keiji,Kotsuki, Hiyoshizo
, p. 5737 - 5740 (2007/10/03)
(Diagram presented) A stereocontrolled route via allyl 1,2-diols to vicinal diamines based on the [3.3] sigmatropic rearrangement of allyl cyanate has been developed. Our approach consists of two consecutive steps: stereoselective construction of allyl an