91790-55-5

Basic information

• Product Name: 7-ethoxy-6-methoxy-4-(3,4-dimethoxybenzylidene)isochroman-3-one
• Synonyms: 7-ethoxy-6-methoxy-4-(3,4-dimethoxybenzylidene)isochroman-3-one
• CAS NO: 91790-55-5
• Molecular Weight: 370.402
• Mol File: 91790-55-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-ethoxy-6-methoxy-4-(3,4-dimethoxybenzylidene)isochroman-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 7-ethoxy-6-methoxy-4-(3,4-dimethoxybenzylidene)isochroman-3-one(91790-55-5)
• EPA Substance Registry System: 7-ethoxy-6-methoxy-4-(3,4-dimethoxybenzylidene)isochroman-3-one(91790-55-5)

Safety Data

• Hazardous Substances Data: 91790-55-5(Hazardous Substances Data)

Upstream product

• 76055-91-9 4-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochroman-3-one 
• 120-25-2 4-ethoxy-3-methoxybenzaldehyde 
• 91790-53-3 1,2,3,4-tetrahydro-6,7-dimethoxy-2-(3,4-dimethoxybenzyl)isoquinoline 
• 18065-77-5 N-(3,4-dimethoxy-β-phenethyl)-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline 
• 120-13-8 4-ethoxy-3-methoxyphenylacetic acid 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 91790-54-4 7-ethoxy-6-methoxyisochroman-3-one 

Downstream Products

• 91790-50-0 7-ethoxy-6-methoxy-4-(3,4-dimethoxybenzyl)isochroman-3-one 

Relevant articles and documents

Electrochemical Oxidation of Aromatic Ethers. Part 9. Proof of the Mode of Aryl-Aryl Coupling in 4-Benzylisochroman-3-ones, and the Oxidative Reactions of 2-and 3-Aralkyl-1,2,3,4-tetrahydroisoquinolines

The influence of the solvent upon the coupling reactions of 4-(3,4-dimethoxybenzyl)-6,7-dimethoxyisochroman-3-one has been studied and it is shown that formation of the product, 7a,8-dihydro-3,10,11-trimethoxy-2H-phenanthrofuran-2,7(5H)-dione, proceeds through a six-membered ring transition state.Anodic oxidation of 2-aralkyl-1,2,3,4-tetrahydroisoquinolines leads to cleavage of the aralkyl substituent, whereas 1,2,3,4-tetrahydro-6,7-dimethoxy-3-(3,4-dimethoxybenzyl)-2-methylisoquinoline cyclises to yield 1,2,3,4-tetrahydro-7,10,11-trimethoxy-3-methyl-2,8a-methanodibenzoazocin-6-one and its 1-hydroxy derivative.