918-19-4

Basic information

• Product Name: Trisilane, 1-chloro-1,1,2,2,3,3,3-heptamethyl-
• Synonyms: 1-Chlor-heptamethyl-trisilan;heptamethyltrisilyl chloride;1-chloroheptamethyltrisilane;Trisilane,1-chloro-1,1,2,2,3,3,3-heptamethyl
• CAS NO: 918-19-4
• Molecular Formula: C7H21ClSi3
• Molecular Weight: 224.953
• Mol File: 918-19-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trisilane, 1-chloro-1,1,2,2,3,3,3-heptamethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Trisilane, 1-chloro-1,1,2,2,3,3,3-heptamethyl-(918-19-4)
• EPA Substance Registry System: Trisilane, 1-chloro-1,1,2,2,3,3,3-heptamethyl-(918-19-4)

Safety Data

• Hazardous Substances Data: 918-19-4(Hazardous Substances Data)

Upstream product

• 865-76-9 decamethyltetrasilane 

Downstream Products

• 38446-42-3 heptamethyl-1-(1-naphthyl)trisilane 
• 116410-55-0 p-heptamethyltrisilylstyrene 
• 136213-35-9 2,2,4,4,5,5,6,6-octamethyl-3-(2,6-xylylimino)-2,4,5,6-tetrasilaheptane 
• 18297-87-5 1-chloroheptamethyltrisiloxane 
• 65-85-0 benzoic acid 

Relevant articles and documents

CHLORINATIVE CLEAVAGE OF PERMETHYLPOLYSILANES INITIATED BY PHOTO-INDUCED ELECTRON TRANSFER

Irradiation od dodecamethylcyclohexasilane (1) in CCl4-CH2Cl2 in the presence of 9,10-dicyanoanthracene (2) afforded 1,6-dichlorododecamethylsilane in 70percent yield.Fluorescence of 2 was quenched by 1 with a diffusion-controlled rate.A mechanism of free-radical chlorination involving (1)+ is proposed.