91804-19-2

Basic information

• Product Name: 2-Furanpropanenitrile, b-oxo-a-phenyl-
• CAS NO: 91804-19-2
• Molecular Formula: C13H9NO2
• Molecular Weight: 211.22
• Mol File: 91804-19-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Furanpropanenitrile, b-oxo-a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Furanpropanenitrile, b-oxo-a-phenyl-(91804-19-2)
• EPA Substance Registry System: 2-Furanpropanenitrile, b-oxo-a-phenyl-(91804-19-2)

Safety Data

• Hazardous Substances Data: 91804-19-2(Hazardous Substances Data)

Upstream product

• 614-99-3 Ethyl 2-furoate 
• 140-29-4 phenylacetonitrile 
• 527-69-5 2-furancarbonyl chloride 
• 75-05-8 acetonitrile 
• 164594-13-2 Phenyl[2-(trimethylsilyl)phenyl]iodonium trifluoromethanesulfonate 
• 98-03-3 thiophene-2-carbaldehyde 

Downstream Products

• 138852-90-1 3-hydroxy-2-phenyl-3-(furan-2-yl)-propionitrile 

Relevant articles and documents

Facile one-pot synthesis of 2-aryl-substituted nitriles and 2-aryl-3-keto nitriles via benzyne reaction

2-Aryl-substituted nitriles were prepared in good to excellent yields in a one-pot reaction by the reaction of benzyne, generated using neutral conditions from (phenyl)[o-(trimethylsilyl)-phenyl]iodonium triflate, and 2-lithionitriles. 3-Keto nitriles substituted at the 2-position were obtained in good yields when these reactions were trapped with acid chlorides. The mechanism of the benzyne reaction in terms of a N-lithiobenzocyclobutanimine intermediate is discussed. Copyright Taylor & Francis Group, LLC.