91852-23-2Relevant articles and documents
Syntheses of linear tetra-, hexa-, and octa-saccharide fragments of the i-blood group active poly-(N-acetyl-lactosamine) series. Blockwise methods for the synthesis of repetitive oligosaccharide sequences.
Alais,Veyrieres
, p. 11 - 31 (2007/10/02)
N-Phthaloylation of lactosamine gave various glycosyl donors (beta-chloride, beta-trichloroacetimidate) and glycosyl acceptors (3',4'-diol). Coupling of the chloride with a methyl beta-D-glycoside led to the tetrasaccharide fragment, beta-D-Galp-(1----4)-
The synthesis of derivatives of lactosamine and cellobiosamine to serve as probes in studies of the combining site of the monoclonal anti-I Ma antibody
Wong, Ting C.,Lemieux, Raymond U.
, p. 1207 - 1213 (2007/10/02)
Syntheses are reported for a variety of structures used in a continuation of our studies of the combinig site of the monoclonal anti-I Ma antibody.These structures include that N-acetyl, N-formyl, and N-pivalyl derivatives of methyl-β-D-lactosaminide, the ethyl, propyl, isopropyl, and isobutyl β-glycosides of N-acetyllactosamine and the βDGal(1->4)βDGlcNAc(1->6)-, βDGal(1->4)βDGlcNH2(1->6)-, βDGal(1->4)βDGlcNCOCF3(1->6)-, and βDGlc(1->4)βDGlcNAc(1->6)-derivatives of 1,2;3,4-di-O-isopropylidene-α-D-galactopyranose.Also, preparations of 6-deoxy-βDGal(1->4)βDGlcNAc(1->6)α,βDGal and βDGlcNAc(1->6)βDGal(1->4)βDGlcNAcOCH3 are described.