91860-98-9Relevant articles and documents
ON THE COMMUNICATION OF CHIRALITY FROM FURANOSE AND PYRANOSE RINGS TO MONOSACCHARIDE SIDE CHAINS: ANOMALOUS RESULTS IN THE GLUCOSE SERIES
Danishefsky, Samuel J.,DeNinno, Michael P.,Phillips, Gary B.,Zelle, Robert E.
, p. 2809 - 2819 (2007/10/02)
The reactions of allyltrimethylsilane with dialdose derivatives occur, under catalysis by boron trifluoride etherate or titanium tetrachloride, with high stereoselectivity, thereby providing simple routes to the corresponding allyl carbinols.The sense of
Chelation-Controlled Facially Selective Cyclocondensation Reactions of Chiral Alkoxy Aldehydes: Syntheses of a Mouse Androgen and of a Carbon-Linked Disaccharide
Danishefsky, Samuel J.,Pearson, William H.,Harvey, Daniel F.,Maring, Clarence J.,Springer, James P.
, p. 1256 - 1268 (2007/10/02)
Magnesium bromide in tetrahydrofuran catalyzes the cycloaddition of a variety of chiral alkoxy aldehydes with activated butadienes.The stereochemistry of these products is such that they can be rationalized as arising from a reacting conformer in which th