91861-49-3

Basic information

• Product Name: (E)-(±)-1-(3-bromobut-1-enyl)benzene
• Synonyms: (E)-(±)-1-(3-bromobut-1-enyl)benzene
• CAS NO: 91861-49-3
• Molecular Weight: 211.101
• Mol File: 91861-49-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-(±)-1-(3-bromobut-1-enyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(±)-1-(3-bromobut-1-enyl)benzene(91861-49-3)
• EPA Substance Registry System: (E)-(±)-1-(3-bromobut-1-enyl)benzene(91861-49-3)

Safety Data

• Hazardous Substances Data: 91861-49-3(Hazardous Substances Data)

Upstream product

• 1896-62-4 (E)-benzalacetone 
• 36004-04-3 ethyl (E)-1-phenylbut-1-en-3-ol 
• 14371-10-9 (E)-3-phenylpropenal 

Downstream Products

• 112528-98-0 (E)-(±)-2-methyl-4-phenylbut-3-enenitrile 
• 79164-23-1 (E)-2-methyl-4-phenylbut-3-enoic acid 
• 935-00-2 trans-4-phenyl-2-butene 
• 1005-64-7 trans-1-phenyl-1-butene 
• 345623-23-6 N,N',2-Triphenyl-4-(triphenylphosphoranyliden)-2-pentendiamid 
• 80922-26-5 5-Methyl-1-(4-methylphenyl)-6-(4-methylphenylamino)3-phenyl-2(1H)-pyridinon 
• 80922-25-4 6-Anilino-5-methyl-1,3-diphenyl-2(1H)-pyridinon 
• 80922-43-6 ((Z)-1-Methyl-3-phenyl-allylidene)-triphenyl-λ⁵-phosphane 
• 80922-32-3 ((E)-2-Methyl-4-phenyl-buta-1,3-dienylidene)-p-tolyl-amine 
• 80922-31-2 ((E)-2-Methyl-4-phenyl-buta-1,3-dienylidene)-phenyl-amine 
• 80922-28-7 N-(Propyl)styrylacetamid 
• 80922-29-8 N-(2-Methyl-4-phenyl-1,3-butadienyliden)propylamin 
• 80922-34-5 ((E)-4-Phenyl-buta-1,3-dienylidene)-propyl-amine 
• 41429-69-0 Triphenylphosphonium-cinnamylid 

Relevant articles and documents

Copper(I)-Catalyzed Allylic Substitutions with a Hydride Nucleophile

An easily accessible copper(I)/N-heterocyclic carbene (NHC) complex enables a regioselective hydride transfer to allylic bromides, an allylic reduction. The resulting aryl- and alkyl-substituted branched α-olefins, which are valuable building blocks for synthesis, are obtained in good yields and regioselectivity. A commercially available silane, (TMSO)2Si(Me)H, is employed as hydride source. This protocol offers a unified alternative to the established metal-catalyzed allylic substitutions with carbon nucleophiles, as no adaption of the catalyst to the nature of the nucleophile is required.

The synthesis of an aziridinyl analogue of unit A of cryptophycin-1

A novel analogue of unit A of cryptophycin-1 was prepared starting from commercial trans-cinnamaldehyde. The modifications introduced into the new structure related to the replacement of the epoxide with an aziridine moiety, and the inclusion of the 1,3-enone moiety into an aromatic ester frame through the synthesis of a key aromatic ketone. Asymmetry was induced during the later steps of the synthetic pathway. The optical purity of compounds was monitored by chiral HPLC and polarimetric measurements.