918655-75-1

Basic information

• Product Name: (E)-1,4-bis(o-hydroxymethylphenoxy)-2-butene
• Synonyms: (E)-1,4-bis(o-hydroxymethylphenoxy)-2-butene
• CAS NO: 918655-75-1
• Molecular Weight: 300.354
• Mol File: 918655-75-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1,4-bis(o-hydroxymethylphenoxy)-2-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,4-bis(o-hydroxymethylphenoxy)-2-butene(918655-75-1)
• EPA Substance Registry System: (E)-1,4-bis(o-hydroxymethylphenoxy)-2-butene(918655-75-1)

Safety Data

• Hazardous Substances Data: 918655-75-1(Hazardous Substances Data)

Upstream product

• 26906-01-4 2-allyloxybenzyl alcohol 
• 918655-71-7 2,2'-[but-2-ene-1,4-diylbis(oxy)]dibenzaldehyde 

Downstream Products

• 918655-67-1 (E)-1,4-bis(o-chloromethylphenoxy)-2-butene 

Relevant articles and documents

Synthesis of olefinic crown diamides and their conversion into pyrazolino macrocycles: Promising photoluminescent crown compounds

Macrocyclic crown diamides with 16- or 24-membered rings containing E- and Z-olefinic double bonds were synthesized either by bisalkylation or by ring-closing metathesis (RCM) techniques. The two methods were evaluated and compared with regard to yield and to product stereochemistry. Isomerization of some Z-olefinic macrocycles to their corresponding E-isomers was achieved using Grubbs' catalyst second generation. Some of the required starting dials, diols and bishalo compounds were prepared by different routes including cross-metathesis (CM). The latter was compared with other investigated methods. Some of the olefinic macrocycles were subjected to cycloaddition reactions with diphenylnitrileimine to give the corresponding pyrazolino macrocycles. The latter showed interesting emission spectra. Georg Thieme Verlag Stuttgart.