918819-06-4

Basic information

• Product Name: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-(4-morpholinyl)-
• CAS NO: 918819-06-4
• Molecular Formula: C15H21NO4
• Molecular Weight: 279.336
• Mol File: 918819-06-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-(4-morpholinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-(4-morpholinyl)-(918819-06-4)
• EPA Substance Registry System: 1-Propanone, 2-[(4-methoxyphenyl)methoxy]-1-(4-morpholinyl)-(918819-06-4)

Safety Data

• Hazardous Substances Data: 918819-06-4(Hazardous Substances Data)

Upstream product

• 27097-66-1 2-hydroxy-1-(morpholin-4-yl)-1-propanone 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 392692-59-0 2-p-methoxybenzyloxy-3-pentanone 
• 312538-65-1 (S)-2-p-Methoxybenzyloxy-3-pentanone 
• 827308-08-7 2-p-methoxybenzyloxy-3-pentanone 

Relevant articles and documents

Enantioselective microbial hydrolysis of dissymmetrical cyclic carbonates with disubstitution

Enantioselective microbial hydrolysis of C1 and C2 dissymmetrical cyclic carbonates with disubstitution (methyl and another groups) has been developed. Pseudomonas diminuta (FU0090), a bacterium, efficiently catalyzes the hydrolysis of five-membered cyclic carbonates. While the trans-substrates are hydrolyzed with low enantioselectivities and/or reactivities, the microbe hydrolyzes the cis-substrates with very high enantioselectivities to afford the corresponding almost optically pure anti-(2R,3S)-diols. On the other hand, six-membered trans-cyclic carbonates are enantioselectively hydrolyzed to afford the corresponding optically active syn-(2R,4R)-diols, although the hydrolysis of the cis-substrates gives racemic compounds. In all cases, the enzyme prefers the (R)-enantiomer for the carbon atom bearing a methyl group.