91910-50-8

Basic information

• Product Name: Benzoic acid, 2,6-bis(2-propenyloxy)-
• CAS NO: 91910-50-8
• Molecular Formula: C13H14O4
• Molecular Weight: 234.252
• Mol File: 91910-50-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2,6-bis(2-propenyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2,6-bis(2-propenyloxy)-(91910-50-8)
• EPA Substance Registry System: Benzoic acid, 2,6-bis(2-propenyloxy)-(91910-50-8)

Safety Data

• Hazardous Substances Data: 91910-50-8(Hazardous Substances Data)

Upstream product

• 54640-04-9 ethyl 2,6-dihydroxybenzoate 

Relevant articles and documents

Overcoming the Deallylation Problem: Palladium(II)-Catalyzed Chemo-, Regio-, and Stereoselective Allylic Oxidation of Aryl Allyl Ether, Amine, and Amino Acids

We report herein a Pd(II)/bis-sulfoxide-catalyzed intramolecular allylic C-H acetoxylation of aryl allyl ether, amine, and amino acids with the retention of a labile allyl moiety. Mechanistically, the reaction proceeds through a distinct double-bond isomerization from the allylic to the vinylic position followed by intramolecular carboxypalladation and the β-hydride elimination pathway. For the first time, C-H oxidation of N-allyl-protected amino acids to furnish five-membered heterocycles through 1,3-syn-addition is established with excellent diastereoselectivity.