919288-51-0

Basic information

• Product Name: Benzoic acid, 5-bromo-4-hydroxy-3-methoxy-2-methyl-, methyl ester
• CAS NO: 919288-51-0
• Molecular Formula: C10H11BrO4
• Molecular Weight: 275.099
• Mol File: 919288-51-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 5-bromo-4-hydroxy-3-methoxy-2-methyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 5-bromo-4-hydroxy-3-methoxy-2-methyl-, methyl ester(919288-51-0)
• EPA Substance Registry System: Benzoic acid, 5-bromo-4-hydroxy-3-methoxy-2-methyl-, methyl ester(919288-51-0)

Safety Data

• Hazardous Substances Data: 919288-51-0(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 109685-13-4 4-hydroxy-3-methoxy-2-methylbenzyl methyl ether 
• 5533-03-9 2-methoxy-4-methoxymethylphenol 
• 18102-32-4 4-hydroxy-3-methoxy-2-methylbenzaldehyde 
• 498-00-0 4-hydroxymethyl-2-methoxyphenol 
• 351379-46-9 5-bromo-4-hydroxy-3-methoxy-2-methyl-benzaldehyde 

Relevant articles and documents

An interesting issue of Diels-Alder selectivity discovered en route to 11-O-debenzoyltashironin

(Diagram presented) The hypervalent iodine-mediated oxidative dearomatization/Diels-Alder cascade was examined in the context of the natural product 11-O-debenzoyltashironin. Interestingly, the regioselectivity of the Diels-Alder reaction can be completely switched by changing the dienophile. Trapping of allyl alcohols during the oxidative dearomatization gives rise to the five-membered acetal, while trapping of allenyl alcohols results in the six-membered acetal.