919288-53-2

Basic information

• Product Name: Phenol, 5-bromo-3-methoxy-2-methyl-4-(phenylmethoxy)-, 1-formate
• CAS NO: 919288-53-2
• Molecular Formula: C16H15BrO4
• Molecular Weight: 351.197
• Mol File: 919288-53-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenol, 5-bromo-3-methoxy-2-methyl-4-(phenylmethoxy)-, 1-formate(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 5-bromo-3-methoxy-2-methyl-4-(phenylmethoxy)-, 1-formate(919288-53-2)
• EPA Substance Registry System: Phenol, 5-bromo-3-methoxy-2-methyl-4-(phenylmethoxy)-, 1-formate(919288-53-2)

Safety Data

• Hazardous Substances Data: 919288-53-2(Hazardous Substances Data)

Upstream product

• 109685-13-4 4-hydroxy-3-methoxy-2-methylbenzyl methyl ether 
• 5533-03-9 2-methoxy-4-methoxymethylphenol 
• 18102-32-4 4-hydroxy-3-methoxy-2-methylbenzaldehyde 
• 498-00-0 4-hydroxymethyl-2-methoxyphenol 
• 351379-46-9 5-bromo-4-hydroxy-3-methoxy-2-methyl-benzaldehyde 
• 919288-52-1 4-benzyloxy-5-bromo-3-methoxy-2-methyl-benzaldehyde 

Downstream Products

• 919288-49-6 4-benzyloxy-5-bromo-3-methoxy-2-methyl-phenol 
• 846543-32-6 toluene-4-sulfonic acid 5-bromo-4-hydroxy-3-methoxy-2-methyl-phenyl ester 
• 919288-50-9 toluene-4-sulfonic acid 4-benzyloxy-5-bromo-3-methoxy-2-methyl-phenyl ester 

Relevant articles and documents

An interesting issue of Diels-Alder selectivity discovered en route to 11-O-debenzoyltashironin

(Diagram presented) The hypervalent iodine-mediated oxidative dearomatization/Diels-Alder cascade was examined in the context of the natural product 11-O-debenzoyltashironin. Interestingly, the regioselectivity of the Diels-Alder reaction can be completely switched by changing the dienophile. Trapping of allyl alcohols during the oxidative dearomatization gives rise to the five-membered acetal, while trapping of allenyl alcohols results in the six-membered acetal.