919299-25-5

Basic information

• Product Name: Benzoic acid, 2,4,5-trifluoro-3-methoxy-, tributylstannyl ester
• CAS NO: 919299-25-5
• Molecular Formula: C20H31F3O3Sn
• Molecular Weight: 495.17
• Mol File: 919299-25-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2,4,5-trifluoro-3-methoxy-, tributylstannyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2,4,5-trifluoro-3-methoxy-, tributylstannyl ester(919299-25-5)
• EPA Substance Registry System: Benzoic acid, 2,4,5-trifluoro-3-methoxy-, tributylstannyl ester(919299-25-5)

Safety Data

• Hazardous Substances Data: 919299-25-5(Hazardous Substances Data)

Upstream product

• 1461-22-9 tributyltin chloride 
• 112811-65-1 3-methoxy-2,4,5-trifluorobenzoic acid 

Relevant articles and documents

Syntheses and crystal structures of di- and triorganotin(IV) derivatives with 2,4,5-trifluoro-3-methoxybenzoic acid

Eight new organotin(IV) complexes with 2,4,5-trifluoro-3-methoxybenzoic acid RnSn(O2CC6HF3OCH3)4-n (n = 3: R = Ph (1), PhCH2 (2), Me (3), n-Bu (4); n = 2: R = Ph (5), PhCH2 (6), Me (7), n-Bu (8)) have been synthesized. All complexes were characterized by elemental, IR, 1H and 13C NMR spectra analyses, and the structures of complexes 1, 3, 7 and 8 were also determined by X-ray crystallography. The geometries at the tin atoms of 1 and 3 are five-coordinated and those of complexes 7 and 8 are six-coordinated. The structures of complexes 1, 3, 7 and 8 have been found to consist of 1D chains built up by intermolecular C-H?F weak hydrogen bonding. Intermolecular C-F?F weak non-hydrogen interactions in the crystal lattice of 3 link the molecules into a 2D network.