92152-55-1

Basic information

• Product Name: Benzenecarbothioic acid, 4-bromo-, S-(4-methylphenyl) ester
• CAS NO: 92152-55-1
• Molecular Formula: C14H11BrOS
• Molecular Weight: 307.211
• Mol File: 92152-55-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 4-bromo-, S-(4-methylphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 4-bromo-, S-(4-methylphenyl) ester(92152-55-1)
• EPA Substance Registry System: Benzenecarbothioic acid, 4-bromo-, S-(4-methylphenyl) ester(92152-55-1)

Safety Data

• Hazardous Substances Data: 92152-55-1(Hazardous Substances Data)

Upstream product

• 106-45-6 para-thiocresol 
• 586-75-4 4-chlorobenzoyl chloride 
• 586-76-5 4-Bromobenzoic acid 
• 698-67-9 p-bromobenzamide 
• 589-87-7 1,4-bromoiodobenzene 
• 106871-53-8 2-(p-tolylthio)-2-oxoacetic acid 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 27047-23-0 <4-Brom-phenacyl>-p-tolyl-sulfid 

Downstream Products

• 61424-52-0 (4-bromobenzyl)diphenylphosphine oxide 

Relevant articles and documents

Method for synthesizing thioester through cross-coupling of visible light-catalyzed sodium sulfinate and acyl chloride

The method takes sodium sulfinate and acyl chloride as raw materials and utilizes 2, 6 - dimethyl -1, 4 - dihydro -3, 5 - pyridine dicarboxylic acid diethyl ester and an organic alkali catalytic system to cross-couple sulfur radicals and acyl radicals und

Method for producing thioesters by means of oxo thio acetic acid compounds

The invention provides a method for preparing thioesters from oxo thio acetic acid compounds. In the presence of a palladium catalyst, a phosphine ligand and an organic solvent, an oxo thio acetic acid compound is decarboxylated and then reacts with an ar

Oxalic Acid Monothioester for Palladium-Catalyzed Decarboxylative Thiocarbonylation and Hydrothiocarbonylation

Oxalic acid monothioester (OAM), an easily accessible and storable reagent, was reported herein as a thioester synthetic equivalent for palladium-catalyzed decarboxylative thiocarbonylation of organohalides and hydrothiocarbonylation of unsaturated carbon-carbon bonds at room temperature with high chemo- and regioselectivity. The reaction is applicable to the synthesis of cysteine-derived thioesters, thus allowing chemical modification of cysteine-containing peptides. Decarboxylation of OAM proceeds through oxidative addition of Pd(0) to the acyl-S bond, which accounts for the very mild reaction conditions.