92157-35-2

Basic information

• Product Name: methyl 3-hydroxy-3-(4-methoxyphenyl)-2,2-dimethylpropionate
• Synonyms: methyl 3-hydroxy-3-(4-methoxyphenyl)-2,2-dimethylpropionate
• CAS NO: 92157-35-2
• Molecular Weight: 238.284
• Mol File: 92157-35-2.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: methyl 3-hydroxy-3-(4-methoxyphenyl)-2,2-dimethylpropionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-hydroxy-3-(4-methoxyphenyl)-2,2-dimethylpropionate(92157-35-2)
• EPA Substance Registry System: methyl 3-hydroxy-3-(4-methoxyphenyl)-2,2-dimethylpropionate(92157-35-2)

Safety Data

• Hazardous Substances Data: 92157-35-2(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 31469-15-5 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene 
• 151721-69-6 methyl 3-(4-methoxyphenyl)-2,2-dimethyl-3-trimethylsilyloxypropionate 

Relevant articles and documents

Cage Like Al-KIT-5 Mesoporous Materials for C-C Bond Formation Reactions under Solvent Free Conditions

The C-C bond forming reactions are of fundamental importance in chemistry. As a result there is ever growing interest for chemists to develop new methods for C-C bond formation. We report here three dimensional nano-cage mesoporous aluminosilicate materia

Mukaiyama aldol reaction of trimethylsilyl enolate with aldehyde catalyzed by CuI

Cuprous iodide has been found to be a very effective catalyst for Mukaiyama aldol reaction of trimethylsilyl ketene acetal with aldehydes. The new catalytic system promotes efficiently the Mukaiyama aldol reaction in DMF to produce corresponding β-hydroxy carbonyl compounds in high yield.

Catalysis of Mukaiyama aldol reactions by a tricyclic aluminum alkoxide Lewis acid

(Chemical Equation Presented) The Mukayiama aldol reaction of aldehydes is efficiently accomplished with a low concentration of the dimeric alumatrane catalyst 2 at mild or subambient temperatures. Our protocol tolerates a wide variety of electron-rich, neutral, and deficient aryl, alkyl, and heterocyclic aldehydes. A wide variety of enol silyl ethers are also tolerated. An intermediate that was isolated provides mechanistic information regarding the role of dimeric 2 in the Mukaiyama aldol reaction. Experimental evidence is presented for the stronger Lewis acidity of 5 compared with F3B.