92231-57-7

Basic information

• Product Name: 3-Oxabicyclo[4.1.0]heptane, 4,4,7,7-tetramethyl-
• CAS NO: 92231-57-7
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 92231-57-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Oxabicyclo[4.1.0]heptane, 4,4,7,7-tetramethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxabicyclo[4.1.0]heptane, 4,4,7,7-tetramethyl-(92231-57-7)
• EPA Substance Registry System: 3-Oxabicyclo[4.1.0]heptane, 4,4,7,7-tetramethyl-(92231-57-7)

Safety Data

• Hazardous Substances Data: 92231-57-7(Hazardous Substances Data)

Upstream product

• 92231-58-8 6,6,9,9-tetramethyl-3,5-dioxa-4-thiabicyclo<6.1.0>nonane 1-oxide 

Relevant articles and documents

Studies of Chrysanthemic Acid Derivatives: Catalyses Reactions of 3-(2-Hydroxymethyl-3,3-dimethylcyclopropyl)-2-methylpropanol and Formation of a Novel Eight-membered Cyclic Sulphite

Acid catalysed reaction of the cyclopropanediol (3) derived from cis-chrysanthemic acid cis-(1) afforded, depending on the reaction conditions, 3-vinyl-2,2,5,5-tetramethyltetrahydrofuran (4) and 4,4,7,7-tetramethyl-3-oxabicycloheptane (5).On treatment with thionyl chloride-pyridine complex there was obtained in addition the eight-membered cyclic sulphite, 6,6,9,9-tetramethyl-3,5-dioxa-4-thiabicyclononane 4-oxide (6).X-Ray analysis confirms a boat-chair conformation with the S=O group trans to the cyclopropane ring in an equatorial situation.Thermal reaction of (6) gave either (4) or a mixture of (5), cis-chrysanthemol (7), and cis-isochrysanthemol (8).