923-69-3

Basic information

• Product Name: CITRONELLAL DIMETHYL ACETAL
• Synonyms: 8,8-dimethoxy-2,6-dimethyl-2-octen;8,8-dimethoxy-2,6-dimethyl-2-Octene;CITRONELLAL DIMETHYL ACETAL;3,7-DIMETHYL-1-OCTENAL DIMETHYL ACETAL;2,6-Dimethyl-8,8-dimethoxy-2-octene;3,7-Dimethyl-6-octenal dimethyl acetal;2-Octene, 8,8-dimethoxy-2,6-dimethyl-;Einecs 213-098-7
• CAS NO: 923-69-3
• Molecular Formula: C₁₂H₂₄O₂
• Molecular Weight: 200.32
• EINECS: 213-098-7
• Mol File: 923-69-3.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 247.3°Cat760mmHg
• Flash Point: 72.2°C
• Appearance: /
• Density: 0.857g/cm³
• Vapor Pressure: 0.0406mmHg at 25°C
• Refractive Index: 1.435
• CAS DataBase Reference: CITRONELLAL DIMETHYL ACETAL(CAS DataBase Reference)
• NIST Chemistry Reference: CITRONELLAL DIMETHYL ACETAL(923-69-3)
• EPA Substance Registry System: CITRONELLAL DIMETHYL ACETAL(923-69-3)

Safety Data

• Hazardous Substances Data: 923-69-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthesis, p. 586, 1986 DOI: 10.1055/s-1986-31717

InChI:InChI=1/C12H24O2/c1-10(2)7-6-8-11(3)9-12(13-4)14-5/h7,11-12H,6,8-9H2,1-5H3

Upstream product

• 2385-77-5 (R)-Citronellal 
• 67-56-1 methanol 
• 106-23-0 3,7-dimethyl-oct-6-enal 
• 57020-54-9 6-hydroxy-3,7-dimethyloctan-1-al 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 22273-97-8 methyl-4 cyclohexenyl-1 methyle cetone 
• 116-09-6 hydroxy-2-propanone 
• 81328-61-2 2-methyl-1-cyclopentene-1-carboxaldehyde 
• 1073-91-2 Tetramethyl-[1,2,4,5]tetroxan 
• 64-18-6 formic acid 
• 132925-17-8 Toluene-4-sulfonic acid (E)-6-hydroxy-4,9-dimethyl-deca-7,9-dienyl ester 

Relevant articles and documents

Synthesis of Functionalized Aliphatic Acid Esters via the Generation of Alkyl Radicals from Silylperoxyacetals

We describe a catalytic method for the synthesis of a variety of functionalized aliphatic acid esters using silylperoxyacetals, which are versatile alkyl radical precursors with a terminal ester moiety. In the presence of an appropriate transition-metal catalyst, the in situ generation of alkyl radicals and the subsequent bond-forming process proceeds smoothly to afford synthetically valuable aliphatic acid derivatives. The present method can be applied to the efficient synthesis of a pharmaceutically important 1,1-diarylalkane motif. In addition, a novel strategy for the synthesis of structurally diverse hydroxy acid derivatives via a C?O bond formation process that utilizes TEMPO has been developed.

An efficient and versatile procedure for the synthesis of acetals from aldehydes and ketones catalyzed by lithium tetrafluoroborate

Acetals are obtained in good to excellent yields by treatment of aldehydes and ketones with trialkyl orthoformate and the corresponding alcohol in the presence of a catalytic amount of lithium tetrafluoroborate. Due to the mild reaction conditions, this method is compatible with acid-sensitive substrates.

70. Cationic Palladium(II), Platinum(II), and Rhodium(I) Complexes as Acetalisation Catalysts

The use of (CF3SO3)2 as a catalyst for the acetalisation of a variety of aldehydes and ketones and for trans-acetalisation is described.It is also shown that (CF3SO3)2 is at least as effective as the corresponding Pd compound, while much lower reaction rates are observed with