923291-65-0

Basic information

• Product Name: 4-methyl-N-(2-styryl-phenyl)-selenobenzimidic acid phenyl ester
• Synonyms: 4-methyl-N-(2-styryl-phenyl)-selenobenzimidic acid phenyl ester
• CAS NO: 923291-65-0
• Molecular Weight: 452.457
• Mol File: 923291-65-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-methyl-N-(2-styryl-phenyl)-selenobenzimidic acid phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-(2-styryl-phenyl)-selenobenzimidic acid phenyl ester(923291-65-0)
• EPA Substance Registry System: 4-methyl-N-(2-styryl-phenyl)-selenobenzimidic acid phenyl ester(923291-65-0)

Safety Data

• Hazardous Substances Data: 923291-65-0(Hazardous Substances Data)

Upstream product

• 552-89-6 2-nitro-benzaldehyde 
• 16721-45-2 triphenyl(phenylmethylene)phosphorane 
• 13066-19-8 2-(2-phenylethenyl)benzenamine 
• 4714-25-4 2-nitrostilbene 
• 785815-16-9 4-methyl-N-(2-styrylphenyl)benzamide 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Amides as precursors of imidoyl radicals in cyclisation reactions

Amides have been successfully used as precursors of imidoyl radicals for radical cyclisation. The amides have been converted to imidoyl selanides via reaction with phosgene to yield imidoyl chlorides followed by reaction with potassium phenylselanide. Imidoyl selanides were reacted with tributyltin hydride (Bu3SnH) as the radical mediator with triethylborane or AIBN as initiators to yield imidoyl radicals for cyclisation reactions. Imidoyl radicals have been cyclised onto alkenes to yield 2,3-substituted-indoles and -quinolines and also onto pyrroles and indoles to give bi- and tricyclic heteroarenes.