92330-46-6

Basic information

• Product Name: Benzenemethanamine, N-(1-methylhexyl)-
• CAS NO: 92330-46-6
• Molecular Formula: C14H23N
• Molecular Weight: 205.343
• Mol File: 92330-46-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-(1-methylhexyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-(1-methylhexyl)-(92330-46-6)
• EPA Substance Registry System: Benzenemethanamine, N-(1-methylhexyl)-(92330-46-6)

Safety Data

• Hazardous Substances Data: 92330-46-6(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 123-82-0 2-heptylamine 
• 110-43-0 n-pentyl methyl ketone 
• 100-46-9 benzylamine 
• 100-47-0 benzonitrile 

Downstream Products

• 123-82-0 (S)-2-heptylamine 
• 123-82-0 (R)-2-heptylamine 

Relevant articles and documents

Intramolecular C?H Amination of N-Alkylsulfamides by tert-Butyl Hypoiodite or N-Iodosuccinimide

1,3-Diamines are an important class of compounds that are broadly found in natural products and are also widely used as building blocks in organic synthesis. Although the intramolecular C?H amination of N-alkylsulfamide derivatives is a reliable method for the construction of 1,3-diamine structures, the majority of these methods involve the use of a transition-metal catalyst. We herein report on a new transition-metal-free method using tert-butyl hypoiodite (t-BuOI) or N-iodosuccinimide (NIS), enabling secondary non-benzylic and tertiary C?H amination reactions to proceed. The cyclic sulfamide products can be easily transformed into 1,3-diamines. Mechanistic investigations revealed that amination reactions using t-BuOI or NIS each proceed via different pathways.

NHC-based coordination polymers as solid molecular catalysts for reductive amination of biomass levulinic acid

A class of robust solid molecular NHC-based catalysts were readily fabricated via self-assembly from a p-phenylene-bridged bis-benzimidazolium salt with selected metal precursors. Among them, the NHC-Ru polymer demonstrated high catalytic activity and excellent stability as a solid molecular catalyst for the solvent-free reductive amination of biomass levulinic acid with inexpensive ammonium formate, furnishing a challenging unprotected 5-methyl-2-pyrrolidone quantitatively at a 0.15 mol% catalyst loading. The solid catalyst was readily recovered and reused for 37 runs without obvious loss of activity. Remarkably, a TON value up to 6.7 × 104 was achieved in a molar-scale reaction with a catalyst loading at 0.001 mol%. Inspired by the results of a preliminary mechanistic study, notably, one-pot tandem reductive reactions of LA with aldehydes or ketones were successfully developed, affording a variety of structurally intriguing and functional N-substituted 5-methyl-2-pyrrolidones in high chemo-selectivity with good to excellent yields.

Efficient preparation of N-benzyl secondary amines via benzylamine-borane mediated reductive amination

An efficient one-pot reductive amination protocol for preparing N-benzyl secondary amines is described.