92386-04-4Relevant articles and documents
Hetero-?-Systems, 9. About the Relationships between Silaethenes and Methylsilylenes
Maier, Guenther,Mihm, Gerhard,Reisenauer, Hans Peter,Littmann, Dieter
, p. 2369 - 2381 (2007/10/02)
Silaethenes 1 and the isomeric methylsilylenes 2 are separately existing species, but can readily be interconverted in an argon matrix via a photochemically induced 1,2-H shift.In case of the thermal excitation in the gas phase examples for both directions have been dedected spectroscopically: the isomerisation of a silaolefin into the corresponding silylene (1d -> 2d) and the formation of a silene from a silylene (2f -> 1f).