92387-87-6

Basic information

• Product Name: dimethylphenylbismuth
• Synonyms: dimethylphenylbismuth
• CAS NO: 92387-87-6
• Molecular Weight: 316.156
• Mol File: 92387-87-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dimethylphenylbismuth(CAS DataBase Reference)
• NIST Chemistry Reference: dimethylphenylbismuth(92387-87-6)
• EPA Substance Registry System: dimethylphenylbismuth(92387-87-6)

Safety Data

• Hazardous Substances Data: 92387-87-6(Hazardous Substances Data)

Upstream product

• 104202-60-0 bis(dimethylbismutho)methane 
• 591-51-5 phenyllithium 
• 82783-70-8 tetramethyldibismuthane 
• 7529-35-3 dimethylbismuthanyl bromide 

Downstream Products

• 593-91-9 trimethylbismuthine 
• 74724-75-7 methyldiphenylbismuthine 
• 20795-53-3 3-phenylcyclohexanone 

Relevant articles and documents

Synthesis of Mixed Substituted Triorganobismuthanes

Sodium dimethylbismuthide, generated from dimethylbismuth bromide and sodium in liquid ammonia, was treated with alkyl halides to produce dimethylalkylbismuthanes, Me2Bi(alk) (alk = C2H5, n-C3H7, n-C4H9, C3H5, i-C3H7) as thermolabile liquids in yields ranging from 70 to 90percent.With methylene chloride bis(dimethylbismutho)methane, (Me2Bi)2CH2, was obtained.Aryldimethylbismuthanes, (aryl)BiMe2, were prepared by treating dimethylbismuth bromide in THF with elemental lithium (-78 deg C) and subsequent reaction with aryl halides (aryl = 4-C6H4CH3, 4-C6H4OCH3, 2,4,6-C6H2(CH3)3).At 90 deg C in an N2-stream, the thermolabile compounds react quantitatively to form diarylmethylbismuthanes, (aryl)2BiMe and Me3Bi. - Keywords: Dimethylalkylbismuthanes, Bis(dimethylbismutho)methane, Aryldimethylbismuthanes, Diarylmethylbismuthanes