92474-77-6Relevant articles and documents
Efficient photocatalytic oxygenation of alkenes by water soluble sensitizer in organic-water biphasic media
Hajimohammadi, Mahdi,Ghasemi, Hoda
, p. 670 - 676 (2016)
A new green, environmentally and economically photooxygenation of olefins by molecular oxygen in the presence of 4-carboxyl tetra phenyl porphyrin (H2TCPP), Rose Bengal (RB), Methylene Blue (MB) and some metallosensitizers (MS) such as cobalt phthalocyaninesulfonate (Coph(SO3H)4), MnTCPPCl, FeTCPPCl and SbTPP(OH)2 as water-soluble sensitizers in organic-water biphasic media at room temperature under visible light was illustrated. The products were obtained with 100% conversion by H2TCPP and 100% selectivity by Coph(SO3H)4. Also in this study, singlet oxygen production as the major route for oxidation of olefins was proved.