92523-34-7

Basic information

• Product Name: (2-chlorophenyl)(imino)(methyl)-λ⁶-sulfanone
• Synonyms: (2-chlorophenyl)(imino)(methyl)-λ⁶-sulfanone
• CAS NO: 92523-34-7
• Molecular Weight: 189.666
• Mol File: 92523-34-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (2-chlorophenyl)(imino)(methyl)-λ⁶-sulfanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2-chlorophenyl)(imino)(methyl)-λ⁶-sulfanone(92523-34-7)
• EPA Substance Registry System: (2-chlorophenyl)(imino)(methyl)-λ⁶-sulfanone(92523-34-7)

Safety Data

• Hazardous Substances Data: 92523-34-7(Hazardous Substances Data)

Upstream product

• 139696-88-1 2-chlorophenyl methyl sulfoxide 
• 17733-22-1 2-chlorothioanisole 

Downstream Products

• 106046-89-3 C₇H₇ClN₂O₃S 

Relevant articles and documents

Rhodium(iii)-catalyzed cascade C-H functionalization/annulation of sulfoximines with iodonium ylides for the synthesis of cyclohexanone-1,2-benzothiazines

A highly efficient Rh(iii)-catalyzed cascade C-H activation/annulation of sulfoximines with iodonium ylides under metal-oxidant-free conditions has been reported. The fused cyclohexanone-1,2-benzothiazine scaffold is readily achieved with a one-pot proces

Nickel-Catalyzed N-Arylation of NH-Sulfoximines with Aryl Halides via Paired Electrolysis

A novel strategy for the N-arylation of NH-sulfoximines has been developed by merging nickel catalysis and electrochemistry (in an undivided cell), thereby providing a practical method for the construction of sulfoximine derivatives. Paired electrolysis is employed in this protocol, so a sacrificial anode is not required. Owing to the mild reaction conditions, excellent functional group tolerance and yield are achieved. A preliminary mechanistic study indicates that the anodic oxidation of a NiII species is crucial to promote the reductive elimination of a C?N bond from the resulting NiIII species at room temperature.

Iron(II)-Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides

Free NH-sulfoximines were directly prepared from sulfoxides through iron catalysis by applying a readily available, shelf-stable hydroxylamine triflic acid salt. No additional oxidant is needed, and the substrate scope is broad, including a range of heter