92527-67-8

Basic information

• Product Name: 2(3H)-Furanone, dihydro-5-methyl-5-[(phenylmethoxy)methyl]-
• CAS NO: 92527-67-8
• Molecular Formula: C13H16O3
• Molecular Weight: 220.268
• Mol File: 92527-67-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2(3H)-Furanone, dihydro-5-methyl-5-[(phenylmethoxy)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(3H)-Furanone, dihydro-5-methyl-5-[(phenylmethoxy)methyl]-(92527-67-8)
• EPA Substance Registry System: 2(3H)-Furanone, dihydro-5-methyl-5-[(phenylmethoxy)methyl]-(92527-67-8)

Safety Data

• Hazardous Substances Data: 92527-67-8(Hazardous Substances Data)

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 624-45-3 levulinic acid methyl ester 

Relevant articles and documents

Improved enantioselection for chiral dirhodium(II) carboxamide-catalysed carbon-hydrogen insertion reactions of tertiary alkyl diazoacetates

Enantiocontrol in C-H insertion reactions of 3° alkyl diazoacetates, which is highly dependent on the catalyst ligand, is greatly enhanced with the use of dirhodium(II) tetrakis[methyl 1-acetylimidazolidin-2-one-4(S)-carboxylate), Rh2(4S-MACIM)4.

A NEW METHOD FOR THE HYDROXYMETHYLATION OF CARBONYL COMPOUNDS

Benzyl chloromethyl ether reacts with carbonyl compounds in the presence of SmI2 to afford alcohols (I), which are subsequently subjected to hydrogenolysis to yield diols (II).