92567-07-2Relevant articles and documents
Spontaneous cleavage of gem-diazides: A comparison of the effects of α-azido and other electron-donating groups on the kinetic and thermodynamic stability of benzyl and alkyl carbocations in aqueous solution
Richard, John P.,Amyes, Tina L.,Jagannadham, Vandanapu,Lee, Yong-Gu,Rice, Douglas J.
, p. 5198 - 5205 (2007/10/02)
The solvolysis reactions of ring-substituted benzylic and 1-propyl gem-diazides in water proceed by a stepwise mechanism through α-azido carbocation intermediates, which are captured by water to give the corresponding aldehyde as the sole detectable produ
Kinetic and thermodynamic stability of α-azidobenzyl carbocations: Putative intermediates in the Schmidt reaction
Amyes, Tina L.,Richard, John P.
, p. 1867 - 1869 (2007/10/02)
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