926031-15-4

Basic information

• Product Name: (S)-(4-fluorophenyl)(naphthalen-1-yl)methanol
• Synonyms: (S)-(4-fluorophenyl)(naphthalen-1-yl)methanol
• CAS NO: 926031-15-4
• Molecular Weight: 252.288
• Mol File: 926031-15-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (S)-(4-fluorophenyl)(naphthalen-1-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(4-fluorophenyl)(naphthalen-1-yl)methanol(926031-15-4)
• EPA Substance Registry System: (S)-(4-fluorophenyl)(naphthalen-1-yl)methanol(926031-15-4)

Safety Data

• Hazardous Substances Data: 926031-15-4(Hazardous Substances Data)

Upstream product

• 848-54-4 tris(4-fluorophenyl)aluminum 
• 66-77-3 1-naphthaldehyde 
• 1765-93-1 4-fluoroboronic acid 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 352-13-6 4-flourophenylmagnesium bromide 

Relevant articles and documents

The inexpensive additive N-methylmorpholine effectively decreases the equivalents of nucleophiles in the catalytic highly enantioselective arylation of aryl aldehydes

Highly enantioselective arylation of aryl aldehydes catalyzed by (S)-H8-BINOL-Ti(Oi-Pr)2 complex in the presence of N-methylmorpholine (NMM) as an effective and inexpensive additive is described for the first time. We found high enan

Synthesis of new benzimidazolium salts and their application in the asymmetric arylation of aldehydes

A series of novel chiral benzimidazolium salts, the precursor of N-heterocyclic carbene ligands, were designed and synthesized from 1,2-dibromobenzene. In situ prepared corresponding carbenes were tested in asymmetric Rh-catalyzed arylation of aromatic aldehydes, affording chiral diarylmethanols with high yields and moderate enantioselectivities.

AlCl3and BDMAEE: A pair of potent reactive regulators of aryl grignard reagents and highly catalytic asymmetric arylation of aldehydes

Figure Presented Cheap, energy-saving, and applicable: With the aid of AlCl3 and BDMAEE [2,2′-oxybis(N,N-dimethylethanamine)], a highly asymmetric catalytic addition of various aryl Grignard reagents to aldehydes was achieved under mild conditions with easily prepared (S)-H 8-BINOL and inexpensive commercially available Ti(OiPr)4 (see scheme), and the reaction could be easily scaled up with no loss of yield and enantioselectivity.