926293-01-8

Basic information

• Product Name: [Pt(2-benzamidobenzenethiolate)2(PPh₃)2]
• CAS NO: 926293-01-8
• Molecular Weight: 1176.25
• Mol File: 926293-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pt(2-benzamidobenzenethiolate)2(PPh₃)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Pt(2-benzamidobenzenethiolate)2(PPh₃)2](926293-01-8)
• EPA Substance Registry System: [Pt(2-benzamidobenzenethiolate)2(PPh₃)2](926293-01-8)

Safety Data

• Hazardous Substances Data: 926293-01-8(Hazardous Substances Data)

Upstream product

• 14221-02-4 tetrakis(triphenylphosphine)platinum 
• 135-57-9 bis(2-benzoylaminophenyl) disulfide 

Relevant articles and documents

Synthesis and characterization of cyclometallated palladium(II) and platinum(II) complexes with amide-thiolate ligands

The redox reaction of bis(2-benzamidophenyl) disulfide (H2L-LH2) with [Pd(PPh3)4] in a 1:1 ratio gave mononuclear and dinuclear palladium(II) complexes with 2-benzamidobenzenethiolate (H2L-), [Pd(H2L-S)2(PPh3)2] (1) and [Pd2(H2L-S)2 (μ-H2L-S)2(PPh3)2] (2). A similar reaction with [Pt(PPh3)4] produced only the corresponding mononuclear platinum(II) complex, [Pt(H2L-S)2(PPh3)2] (3). Treatment of these complexes with KOH led to the formation of cyclometallated palladium(II) and platinum(II) complexes, [Pd(L-C,N,S)(PPh3)]- ([4]-) and [Pt(L-C,N,S) (PPh3)]- ([5]-). The molecular structures of 2, 3 and [4]- were determined by X-ray crystallography.