92639-43-5

Basic information

• Product Name: Phosphonic acid, [2-hydroxy-1-methyl-3-phenyl-2-(phenylmethyl)propyl]-, dimethyl ester
• CAS NO: 92639-43-5
• Molecular Formula: C19H25O4P
• Molecular Weight: 348.379
• Mol File: 92639-43-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [2-hydroxy-1-methyl-3-phenyl-2-(phenylmethyl)propyl]-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [2-hydroxy-1-methyl-3-phenyl-2-(phenylmethyl)propyl]-, dimethyl ester(92639-43-5)
• EPA Substance Registry System: Phosphonic acid, [2-hydroxy-1-methyl-3-phenyl-2-(phenylmethyl)propyl]-, dimethyl ester(92639-43-5)

Safety Data

• Hazardous Substances Data: 92639-43-5(Hazardous Substances Data)

Upstream product

• 102-04-5 1,3-Diphenylpropanone 
• 6163-75-3 dimethyl ethylphosphonate 

Downstream Products

• 40558-71-2 1,1-Dibenzylpropene 
• 7351-83-9 dimethyl phosphate anion 

Relevant articles and documents

The Olefin Synthesis from β-Hydroxyalkylphosphonates Induced by Fluorides or Relatively Weak Bases

β-Hydroxyalkylphosphonates, which were prepared readily from alkylphosphonates and carbonyl compounds, were treated with a fluoride ion such as CsF or with relatively weak bases such as K2CO3 in N,N-dimethylformamide to give the corresponding olefins in good yields. One molar equivalent of water to bases is effective for increasing the yields of olefins. The stereochemistry of erythro-dimethyl (2-hydroxy-1-methyl-2-phenyl)ethylphosphonate was determined by X-ray crystallographic analysis. Use of threo-isomer gave (E)-olefin exclusively, while that of erythro-enricned isomer afforded predominantly (Z)-olefin, indicating that the present olefination proceeds stereospecifically in a manner of syn-elimination.