92655-82-8

Basic information

• Product Name: methyl 7-(4-methoxyphenyl)-7-oxoheptanoate
• Synonyms: methyl 7-(4-methoxyphenyl)-7-oxoheptanoate
• CAS NO: 92655-82-8
• Molecular Weight: 264.321
• Mol File: 92655-82-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 7-(4-methoxyphenyl)-7-oxoheptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 7-(4-methoxyphenyl)-7-oxoheptanoate(92655-82-8)
• EPA Substance Registry System: methyl 7-(4-methoxyphenyl)-7-oxoheptanoate(92655-82-8)

Safety Data

• Hazardous Substances Data: 92655-82-8(Hazardous Substances Data)

Upstream product

• 818-57-5 Methyl 4-pentenoate 
• 139488-44-1 mercapto-1-(4’-methoxyphenyl)ethanone 
• 66800-56-4 N-methoxycarbonyl-6-aminohexanoic acid 
• 70288-80-1 6-methoxycarbonylaminohexanoic acid methyl ester 
• 123-11-5 4-methoxy-benzaldehyde 

Relevant articles and documents

A metal-free desulfurizing radical reductive C-C coupling of thiols and alkenes

An intermolecular reductive C-C coupling of electrophilic alkyl radicals and alkenes has been developed. Thiols were used as both hydrogen-donating reagents and alkyl radical precursors in the presence of triethyl phosphite and radical initiator. A wide range of alkenes, including styrenes, and aliphatic olefins were well tolerated in this transformation. Mechanistic studies indicated that a phosphite promoted radical desulfurization of thiols to access electrophilic alkyl radicals and a radical chain propagation process may be involved in this transformation.