92694-51-4

Basic information

• Product Name: 2(5H)-Furanone, 5-methyl-, (S)-
• CAS NO: 92694-51-4
• Molecular Formula: C5H6O2
• Molecular Weight: 98.09990
• Mol File: 92694-51-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 40-42 °C(Press: 1.3 Torr)
• Density: 1.095±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2(5H)-Furanone, 5-methyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(5H)-Furanone, 5-methyl-, (S)-(92694-51-4)
• EPA Substance Registry System: 2(5H)-Furanone, 5-methyl-, (S)-(92694-51-4)

Safety Data

• Hazardous Substances Data: 92694-51-4(Hazardous Substances Data)

Upstream product

• 591-11-7 5-methyl-5H-furan-2-one 

Downstream Products

• 214210-36-3 (3S,4R,5S)-4-(dimethylphenylsilyl)-3-hexyl-4,5-dihydro-5-methyl-2(3H)-furanone 
• 19041-15-7 (S)-γ-valerolactone 
• 625080-93-5 (2R,6S)-2-[2-Benzenesulfonyl-1-benzoyloxy-2-((1S,3S,3aS,4S,4aS,8aR,9aS)-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan-4-yl)-ethyl]-6-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 478915-61-6 (2S,6R)-tert-butyl 2-[2-benzenesulfonyl-1-benzoyl-2-[(1S,3S,3aR,4R,4aS,8aR,9aS)-dodecahydro-1-methoxy-3-methylnaphtho[2,3-c]furan-4-yl]ethenyl]-6-methylpiperidine-1-carboxylate 
• 625080-90-2 (2R,6S)-2-[2-Benzenesulfonyl-1-hydroxy-2-((1S,3S,3aS,4S,4aS,8aR,9aS)-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan-4-yl)-ethyl]-6-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 503443-63-8 2-Benzenesulfonyl-2-((1S,3S,3aS,4R,4aS,8aR,9aS)-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan-4-yl)-1-(6-methyl-pyridin-2-yl)-ethanol 
• 503443-65-0 2-Benzenesulfonyl-2-((1S,3S,3aS,4R,4aS,8aR,9aS)-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan-4-yl)-1-(1-methyl-1H-imidazol-2-yl)-ethanol 
• 503443-39-8 (S)-1-Benzyl-3-((1S,3S,3aR,4R,4aS,8aR,9aS)-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan-4-ylmethoxy)-pyrrolidine 
• 503443-53-6 (1S,3S,3aS,4S,4aS,8aR,9aS)-dodecahydro-1-methoxy-3-methyl-4-(phenylsulfonyl)methylnaphtho[2,3-c]furan 
• 503443-52-5 (1S,3S,3aS,4S,4aS,8aR,9aS)-dodecahydro-1-methoxy-3-methyl-4-(phenylsulfonyl)methylnaphtho[2,3-c]furan 
• 192133-57-6 (2R,6S)-2-[2-Benzenesulfonyl-1-hydroxy-2-((1S,3S,3aS,4R,4aS,8aR,9aS)-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan-4-yl)-ethyl]-6-methyl-piperidine-1-carboxylic acid tert-butyl ester 
• 192133-39-4 (1S,3S,3aS,4R,4aS,8aR,9aS)-dodecahydro-1-methoxy-3-methyl-4-[(phenylsulfonyl)methyl]naphtho[2,3-c]furan 
• 192133-37-2 (1S,3S,3aS,4R,4aS,8aR,9aS)-1-Methoxy-3-methyl-4-phenylsulfanylmethyl-dodecahydro-naphtho[2,3-c]furan 

Relevant articles and documents

Kinetic resolution of racemic lactones by conjugate additions of allylic organolithium species: Direct formation of three contiguous centers with high diastereo- and enantioselectivities

(Matrix presented) Kinetic resolution of racemic α,β-unsaturated lactones by the organolithium species produced from asymmetric lithiation of N-Boc-N-(p-methoxyphenyl)cinnamylamine provides conjugate addition products with three contiguous stereogenic centers in yields of 62-77% with diastereomeric ratios from 75:25 to >99:1 and enantiomeric ratios for the major diastereomers from 94:6 to 98:2.