92723-40-5Relevant articles and documents
OXIDATIVE DECOMPOSITION OF tert-BUTYLPHENYL ACETATE
Voronina, S. G.,Perkel', A. L.,Freidin, B. G.
, p. 1700 - 1704 (2007/10/02)
The dependence was studied of the rate of radical-chain oxidation of tert-butylphenyl acetate on temperature, and also the kinetics of product accumulation under conditions of initiated and autooxidation.Recombination of peroxy radicals of tert-butylphenyl acetate proceeds with and without chain termination with formation in the latter case of oxyl radicals, which undergo fragmentation.Under conditions of autooxidation, a product responsible for degenerated branching is tert-butyl-α-hydroperoxyphenyl acetate, the homolysis of which is also associated with fragmentation through intermediate oxyl radicals.