927670-19-7Relevant articles and documents
A biosynthetically-inspired synthesis of the tetrahydrofuran core of obtusallenes II and IV
Braddock, D. Christopher,Bhuva, Roshni,Millan, David S.,Perez-Fuertes, Yolanda,Roberts, Craig A.,Sheppard, Richard N.,Solanki, Savade,Stokes, Elaine S. E.,White, Andrew J. P.
, p. 445 - 448 (2007/10/03)
Sharpless asymmetric dihydroxylation was regioselective for the frans olefin in an E vs Z vs terminal triene substrate. To test a biosynthetic hypothesis, the resulting diol underwent diastereoselective bromoetherification to provide the des-chloro core o