928342-01-2

Basic information

• Product Name: N,N'-di(3,4,5-tridodecylphenyl)-1,7-dibromoperylene-3,4:9,10-tetracarboxylic acid bisimide
• Synonyms: N,N'-di(3,4,5-tridodecylphenyl)-1,7-dibromoperylene-3,4:9,10-tetracarboxylic acid bisimide
• CAS NO: 928342-01-2
• Molecular Weight: 1710.28
• Mol File: 928342-01-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N'-di(3,4,5-tridodecylphenyl)-1,7-dibromoperylene-3,4:9,10-tetracarboxylic acid bisimide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-di(3,4,5-tridodecylphenyl)-1,7-dibromoperylene-3,4:9,10-tetracarboxylic acid bisimide(928342-01-2)
• EPA Substance Registry System: N,N'-di(3,4,5-tridodecylphenyl)-1,7-dibromoperylene-3,4:9,10-tetracarboxylic acid bisimide(928342-01-2)

Safety Data

• Hazardous Substances Data: 928342-01-2(Hazardous Substances Data)

Upstream product

• 885111-15-9 3,4,5-tridodecyl aminobenzene 
• 118129-60-5 1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride 

Relevant articles and documents

Effect of core twisting on self-assembly and optical properties of perylene bisimide dyes in solution and columnar liquid crystalline phases

A series of highly soluble and fluorescent core-twisted perylene bisimide dyes (PBIs) 3a-f with different substituents at the bay area (1,6,7,12 positions of the perylene core) were synthesized and fully characterized by 1H NMR, UV/Vis spectroscopy, MS spectrometry, and elemental analysis. The π-π aggregation properties of these new functional dyes were investigated in detail both in solution and in condensed phase by UV/Vis and fluorescence spectroscopy, vapor pressure osmometry (VPO), differential scanning calorimetry (DSC), polarizing optical microscopy (POM), and X-ray diffraction. Concentration-dependent UV/ Vis measurements and VPO analysis revealed that these core-twisted π-conjugated systems show distinct self-dimerization equilibria in apolar solvent methylcyclohexane (MCH) with dimerization constants between 1.3 × 104 and 30 M-1. The photoluminescence spectra of the dimers of PBIs 3a-f exhibit bathochromic shifts of quite different magnitude which could be attributed to different longitudinal or rotational offsets between the dyes as well as differ ences in the respective π-π stacking distance. In condensed state, quite a few of these PBIs form luminescent rectangular or hexagonal columnar liquid crystalline phases with low isotropization temperatures. The effects of the distortion of the π systems on their π-π stacking and the optical properties of the resultant stacks in solution and in LC phases have been explored in detail. In one case (3a) a particularly interesting phase change from crystalline into liquid crystalline could be observed upon annealing that was accompanied by a transformation from non-fluorescent H-type into strongly fluorescent J-type packing of the dyes.