92855-12-4

Basic information

• Product Name: Benzenamine, 2-(1-naphthalenyl)-
• CAS NO: 92855-12-4
• Molecular Formula: C16H13N
• Molecular Weight: 219.286
• Mol File: 92855-12-4.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-(1-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(1-naphthalenyl)-(92855-12-4)
• EPA Substance Registry System: Benzenamine, 2-(1-naphthalenyl)-(92855-12-4)

Safety Data

• Hazardous Substances Data: 92855-12-4(Hazardous Substances Data)

Upstream product

• 615-43-0 2-iodophenylamine 
• 32316-92-0 naphthalene-2-boronic acid 
• 68716-52-9 1-naphthylboronic acid pinacol ester 
• 90-11-9 1-Bromonaphthalene 
• 13922-41-3 1-Naphthylboronic acid 
• 615-36-1 2-bromoaniline 
• 90-14-2 1-Iodonaphthalene 
• 577-19-5 2-nitrophenyl bromide 
• 21792-52-9 1,2-diethynylbenzene 
• 62-53-3 aniline 
• 5415-59-8 1-(2-nitrophenyl)naphthalene 

Downstream Products

• 206262-63-7 2-[1]naphthyl-benzenesulfonyl chloride 
• 605-02-7 1-phenylnaphthalene 
• 206-44-0 fluoranthene 
• 64954-44-5 6-phenylbenzo[c]phenanthrene 
• 205-25-4 benzo[c]carbazole 
• 13177-27-0 7-Amino-fluoranthen 
• 109810-71-1 acetic acid-(2-[1]naphthyl-anilide) 
• 92858-87-2 1-(2-azido-phenyl)-naphthalene 
• 66644-28-8 formic acid-(2-[1]naphthyl-anilide) 
• 18937-93-4 1-(2-iodophenyl)naphthalene 

Relevant articles and documents

Synthesis of Polyethylenes with Controlled Branching with α-Diimine Nickel Catalysts and Revisiting Formation of Long-Chain Branching

The synthesis of polyethylenes with precise branching, especially long-chain branching (LCB), using ethylene monomer as a single feedstock is of a significant academic and industrial interest. On the basis of the ortho-aryl effect, a series of α-diimine n

Radical Borylative Cyclization of Isocyanoarenes with N-Heterocyclic Carbene Borane: Synthesis of Borylated Aza-arenes

Borylated aza-arenes are of great importance in the area of organic synthesis. A radical borylative cyclization of isocyanoarenes with N-heterocyclic carbene borane (NHC-BH3) under metal-free conditions was developed. The reaction allows the efficient assembly of several types of borylated aza-arenes (phenanthridines, benzothiazoles, etc.), which are difficult to access using alternative methods. Mild reaction conditions, a good functional-group tolerance, and generally good efficiencies were observed. The utility of these products is demonstrated, and the mechanism is discussed.

Atmosphere-Controlled Palladium-Catalyzed Divergent Decarboxylative Cyclization of 2-Iodobiphenyls and α-Oxocarboxylic Acids

A novel palladium-catalyzed divergent decarboxylative cyclization of 2-iodobiphenyls and α-oxocarboxylic acids utilizing the atmosphere as a controlled switch is reported. Under the protection of a nitrogen atmosphere, tribenzotropones are synthesized by a [4 + 3] decarboxylative cyclization. Employing a palladium/O2 system enables a [4 + 2] decarboxylative cyclization to assemble triphenylenes. Notably, preliminary mechanistic studies indicate that the formation of triphenylenes involves a double decarboxylation.