928758-07-0

Basic information

• Product Name: 1-(4-vinylphenyl)-2-methylpropan-1-one
• Synonyms: 1-(4-vinylphenyl)-2-methylpropan-1-one
• CAS NO: 928758-07-0
• Molecular Weight: 174.243
• Mol File: 928758-07-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(4-vinylphenyl)-2-methylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-vinylphenyl)-2-methylpropan-1-one(928758-07-0)
• EPA Substance Registry System: 1-(4-vinylphenyl)-2-methylpropan-1-one(928758-07-0)

Safety Data

• Hazardous Substances Data: 928758-07-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 10537-63-0 1-(4-vinylphenyl)ethanone 
• 1073-67-2 4-vinylbenzyl chloride 
• 7459-73-6 (4-Vinylphenyl)magnesium chloride 
• 97-72-3 2-Methylpropionic anhydride 

Downstream Products

• 928758-04-7 4-(1-isopropylvinyl)styrene 

Relevant articles and documents

Methylation of C(sp3)-H/C(sp2)-H bonds with methanol catalyzed by cobalt system

A highly efficient Co-based catalytic system, composed of a commercially available Co salt, a tetradentate phosphine ligand P-(CH2CH2PPh2)3(PP3), and a base (denoted as [Co]/PP3/base), is developed for the methylation of C(sp3)-H and C(sp2)-H bonds using methanol as a methylating reagent. The Co(BF4)2.6H2O/PP3/K2CO3 catalytic system showed high catalytic activity for the methylation of C-H bonds in aryl alkyl ketones, aryl acetonitriles, and indoles, with wide substrate scope and good functional group tolerance, and methylsubstituted products were obtained in good to excellent yields at 100 °C. This cheap, readily available, and highly efficient Co-based catalytic system may have promising applications in methylation reaction using methanol.