929097-27-8

Basic information

• Product Name: Bicyclo[2.2.2]octan-2-one, 5-(1,1-dimethylethoxy)-7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-hydroxy -4-methyl-, (1R,3R,4S,5S,7S)-
• CAS NO: 929097-27-8
• Molecular Formula: C19H36O4Si
• Molecular Weight: 356.578
• Mol File: 929097-27-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.2]octan-2-one, 5-(1,1-dimethylethoxy)-7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-hydroxy -4-methyl-, (1R,3R,4S,5S,7S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.2]octan-2-one, 5-(1,1-dimethylethoxy)-7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-hydroxy -4-methyl-, (1R,3R,4S,5S,7S)-(929097-27-8)
• EPA Substance Registry System: Bicyclo[2.2.2]octan-2-one, 5-(1,1-dimethylethoxy)-7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-hydroxy -4-methyl-, (1R,3R,4S,5S,7S)-(929097-27-8)

Safety Data

• Hazardous Substances Data: 929097-27-8(Hazardous Substances Data)

Upstream product

• 929097-26-7 7-tert-butoxy-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-trimethylsilanyloxy-bicyclo[2.2.2]oct-2-ene 

Downstream Products

• 929097-51-8 5-tert-butoxy-2-(tert-butyl-dimethyl-silanyloxy)-4-formyl-4-methyl-cyclohexane carboxylic acid 
• 952717-64-5 2-tert-butoxy-5-(tert-butyl-dimethyl-silanoxy)-1-methyl-cyclohexane-1,4-dicarboxylic acid 

Relevant articles and documents

Synthesis of chiral ligands from hydrindene diols with a consecutive heterodomino transformation as the key reaction step

We report here the elaboration of a bicyclo[2.2.2]octane system, synthesized by a consecutive domino process, towards highly functionalized stereopure derivatives, which could be used as multidentate ligands for the generation of asymmetric catalysts. Wil