92912-56-6

Basic information

• Product Name: Piperidine, 1-[(3-methoxyphenyl)acetyl]-
• CAS NO: 92912-56-6
• Molecular Formula: C14H19NO2
• Molecular Weight: 233.31
• Mol File: 92912-56-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Piperidine, 1-[(3-methoxyphenyl)acetyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 1-[(3-methoxyphenyl)acetyl]-(92912-56-6)
• EPA Substance Registry System: Piperidine, 1-[(3-methoxyphenyl)acetyl]-(92912-56-6)

Safety Data

• Hazardous Substances Data: 92912-56-6(Hazardous Substances Data)

Upstream product

• 110-89-4 piperidine 
• 6834-42-0 3-methoxyphenylacetic acid chloride 
• 253684-23-0 1,1-dibromo-2-(3-methoxyphenyl)ethene 

Downstream Products

• 461389-78-6 1-[2-(3-methoxyphenyl)ethyl]piperidine 
• 121557-96-8 (Z)-Methyl <1-<(3-Ethoxy-3-oxopropyl)thio>-2-(3-methoxyphenyl)ethylidene>hydrazinocarboxylate 
• 121557-97-9 (E)-Methyl <1-<(3-Ethoxy-3-oxopropyl)thio>-2-(3-methoxyphenyl)ethylidene>hydrazinocarboxylate 
• 114393-45-2 3-[5-(3-Methoxy-phenyl)-[1,2,3]thiadiazol-4-ylsulfanyl]-propionic acid ethyl ester 
• 114373-92-1 2-[2-(3-methoxyphenyl)-1-thioxoethyl]hydrazinecarboxylic acid, methyl ester 
• 121557-83-3 Ethyl <<2-(3-Methoxyphenyl)-1-thioxoethyl>thio>acetate 
• 118511-59-4 1-[2-(3-hydroxyphenyl)ethyl]piperidine 
• 114373-93-2 N-<2-(3-Methoxyphenyl)-1-thioxoethyl>piperidine 

Relevant articles and documents

A facile one-carbon homologation of aryl aldehydes to amides.

The easily accessible 2-aryl-1,1-dibromo-1-alkenes can be converted to amides under unusually mild conditions in good to excellent yields. Both electron-donating and electron-withdrawing substitutions on the aromatic rings are tolerated, and the reaction works well with hindered alkylamines. This simple homologation could find broad applications. [reaction: see text]

Electro-organic Reactions. Part 22. An Entry into the Quinolizidine and Benzoquinolizidine Ring Systems via Anodic Methoxylation

Examples of the quinolizidine and benzoquinolizidine ring systems (1,1-bisethoxycarbonyl-4-oxo-quinolizidine, 1,3,4,6,7,11b-hexahydro-2H-benzoquinolizidine, and 1,2-t-butyl-3,4,6,7,11b-hexahydro-2H-benzo-quinolizidine) have been synthesized by routes which involve initial anodic methoxylation of piperidine precursors with subsequent intramolecular Lewis acid-catalysed cyclisation reactions.Reaction conditions for such cyclisations have been explored; success depends on a correct choice of catalyst (usually aluminium chloride) and, critically, on steric factors.The stereochemistry of the cyclic products has been established and the stereochemical course of the reactions is commented upon.