930599-20-5Relevant articles and documents
A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction
Movassaghi, Mohammad,Ahmad, Omar K.
supporting information; experimental part, p. 8909 - 8912 (2009/05/26)
(Chemical Equation Presented) One step beyond: The first single-step stereospecific transition-metal-catalyzed conversion of allylic electrophiles into monoalkyl diazenes is described. This synthesis of allylic monoalkyl diazenes offers a new strategy for asymmetric synthesis by the reduction of optically active substrates or the use of chiral catalyst systems. Sensitive substrates are reduced in a highly selective manner. Ar = 2-NO2C 6H2.