930806-58-9Relevant articles and documents
Bench-Stable N-Heterocyclic Carbene Nickel Precatalysts for C?C and C?N Bond-Forming Reactions
Strieth-Kalthoff, Felix,Longstreet, Ashley R.,Weber, Jessica M.,Jamison, Timothy F.
, p. 2873 - 2877 (2018/05/07)
Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type me
Highly selective coupling of alkenes and aldehydes catalyzed by [Ni(NHC){P(OPh)3}]: Synergy between a strong σ donor and a strong π acceptor
Ho, Chun-Yu,Jamison, Timothy F.
, p. 782 - 785 (2007/10/03)
(Chemical Equation Presented) Give and take: Both a strong electron donor (1) and a strong electron acceptor (P(OPh)3) are necessary for a highly selective, nickel-catalyzed coupling reaction between alkenes, aldehydes, and silyl triflates (see