931119-44-7

Basic information

• Product Name: (1,3-Dioxo-1,3-dihydro-isoindol-2-yloxy)-phenyl-acetic acid benzyl ester
• Synonyms: (1,3-Dioxo-1,3-dihydro-isoindol-2-yloxy)-phenyl-acetic acid benzyl ester
• CAS NO: 931119-44-7
• Molecular Weight: 387.392
• Mol File: 931119-44-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1,3-Dioxo-1,3-dihydro-isoindol-2-yloxy)-phenyl-acetic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1,3-Dioxo-1,3-dihydro-isoindol-2-yloxy)-phenyl-acetic acid benzyl ester(931119-44-7)
• EPA Substance Registry System: (1,3-Dioxo-1,3-dihydro-isoindol-2-yloxy)-phenyl-acetic acid benzyl ester(931119-44-7)

Safety Data

• Hazardous Substances Data: 931119-44-7(Hazardous Substances Data)

Upstream product

• 524-38-9 N-hydroxyphthalimide 
• 102-16-9 benzyl 2-phenylacetate 
• 62173-99-3 benzyl 2-hydroxy-2-phenylacetate 

Relevant articles and documents

Unraveling two pathways for NHPI-mediated electrocatalytic oxidation reaction

Two pathways for N-hydroxyphthalimide (NHPI)-mediated electrocatalytic oxidation using phenylacetate derivatives as template substrates were first reported for benzylic C[sbnd]H oxidation to oxygenated and non-oxygenated products. DFT calculation indicates that the hydrogen-atom transfer (HAT) process between phthalimido-N-oxyl (PINO) and substrate is a rate-determined step. Aromatic α-keto esters and 2-((1,3-dioxoisoindolin-2-yl)oxy)-2-aryl acetate obtained by cross-coupling between benzylic radical and PINO can be selectively synthesized through controlling the concentration of PINO radical. This method provides a deep understanding for selective weak C[sbnd]H oxidation using NHPI as redox mediator.