931430-51-2

Basic information

• Product Name: 2-phenylvinylboronic acid
• Synonyms: 2-phenylvinylboronic acid
• CAS NO: 931430-51-2
• Molecular Weight: 266.096
• Mol File: 931430-51-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-phenylvinylboronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenylvinylboronic acid(931430-51-2)
• EPA Substance Registry System: 2-phenylvinylboronic acid(931430-51-2)

Safety Data

• Hazardous Substances Data: 931430-51-2(Hazardous Substances Data)

Upstream product

• 288101-48-4 2-(2,4-difluorophenyl)-4,4, 5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Speciation control during Suzuki-Miyaura cross-coupling of haloaryl and haloalkenyl MIDA boronic esters

Boronic acid solution speciation can be controlled during the Suzuki-Miyaura cross-coupling of haloaryl N-methyliminodiacetic acid (MIDA) boronic esters to enable the formal homologation of boronic acid derivatives. The reaction is contingent upon control of the basic biphase and is thermodynamically driven: temperature control provides highly chemoselective access to either BMIDA adducts at room temperature or boronic acid pinacol ester (BPin) products at elevated temperature. Control experiments and solubility analyses have provided some insight into the mechanistic operation of the formal homologation process.