93292-61-6

Basic information

• Product Name: tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane
• Synonyms: tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane
• CAS NO: 93292-61-6
• Molecular Weight: 440.698
• Mol File: 93292-61-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane(93292-61-6)
• EPA Substance Registry System: tert-Butyl-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hexyloxy]-diphenyl-silane(93292-61-6)

Safety Data

• Hazardous Substances Data: 93292-61-6(Hazardous Substances Data)

Upstream product

• 128142-58-5 Naphthalene-2-sulfonic acid (S)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-ethyl ester 
• 128142-57-4 5,6-O-isopropylidene-2,3-di-O-methyl-D-araboascobate 
• 114184-97-3 (S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)ethane-1,2-diol 
• 50271-42-6 5,6-O-isopropylidene-D-isoascorbic acid 
• 93292-42-3 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose 
• 93292-41-2 2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-O-isopropylidene-D-erythro-pentose diethyl dithioacetal 

Downstream Products

• 94292-89-4 4-{(4S,5R)-5-[(1E,3E,5E,7E)-(S)-9-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-1,3,5,7-tetraenyl]-2-oxo-[1,3]dioxolan-4-yl}-butyric acid ethyl ester 
• 94235-56-0 (5S,6R,15S)-(7E,9E,11Z,13E)-15-O-tert-butyldiphenylsilyl-5,6-O-carbonyllipoxin A₄ ethyl ester 
• 133988-97-3 ethyl (4S)-(2E)-4-tert-butyldiphenylsilyloxy-2-nonenoate 
• 93292-65-0 1-bromo-(4S),(2E)-4-tert-butyldiphenylsilyloxy-2-nonene 
• 118908-15-9 (E)-(S)-4-(tert-Butyl-diphenyl-silanyloxy)-non-2-enal 
• 80234-66-8 8(S),15(S),5Z,9,11,13E-diHETE 
• 80234-67-9 8(R),15(S),5Z,9,11,13E-diHETE 
• 77667-08-4 8(R),15(S) dihydroxy 5Z,9E,11E,13Z eicosatetraenoic acid 
• 93292-69-4 (5Z,9E,11E,13E)-(8S,15S)-8,15-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-5,9,11,13-tetraenoic acid methyl ester 
• 93292-67-2 (5Z,9E,11E,13Z)-(8S,15S)-8,15-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-5,9,11,13-tetraenoic acid methyl ester 
• 93292-70-7 (5Z,9E,11E,13E)-(8R,15S)-8,15-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-5,9,11,13-tetraenoic acid methyl ester 
• 93292-68-3 (5Z,9E,11E,13Z)-(8R,15S)-8,15-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-5,9,11,13-tetraenoic acid methyl ester 
• 93292-66-1 <(4S)-(2E)-4-tert-butyldiphenylsilyloxy-2-nonen-yl>triphenylphosphonium bromide 
• 93292-64-9 (4S),(2E)-4-O-tert-butyldiphenylsilyloxy-2-nonenol 

Relevant articles and documents

CHIRAL α-HYDROXY- AND α,β-DIHYDROXY-ALDEHYDES FROM D-ISOASCORBIC AND L-ASCORBIC ACIDS. USEFUL PRECURSORS FOR THE SYNTHESIS OF FATTY ACID METABOLITES.

The four possible stereoisomers of α,β-dihydroxyaldehydes, useful building blocks for the synthesis of fatty acids metabolites, are synthesized via epoxy-tetrols derived from D-isoascorbic and L-ascorbic acids.The general method we develop allows the synthesis of chiral α-hydroxyaldehydes as well.