93366-73-5

Basic information

• Product Name: 2-(phenethylthio)benzo[d]thiazole
• Synonyms: 2-(phenethylthio)benzo[d]thiazole
• CAS NO: 93366-73-5
• Molecular Weight: 271.407
• Mol File: 93366-73-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-(phenethylthio)benzo[d]thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(phenethylthio)benzo[d]thiazole(93366-73-5)
• EPA Substance Registry System: 2-(phenethylthio)benzo[d]thiazole(93366-73-5)

Safety Data

• Hazardous Substances Data: 93366-73-5(Hazardous Substances Data)

Upstream product

• 615-22-5 2-methylmercaptobenzothiazole 
• 100-39-0 benzyl bromide 
• 95-16-9 1,3-Benzothiazole 
• 103-63-9 1-phenyl-2-bromoethane 
• 149-30-4 2-Mercaptobenzothiazole 
• 849604-79-1 2-phenylethyl diphenylphosphinite 
• 60-12-8 2-phenylethanol 
• 4410-99-5 2-mercaptophenylethane 
• 106296-62-2 2-benzothiazol-2-ylthio(trimethylsilyl)ethanol 
• 149-30-4 2-thioxo-3H-1,3-benzothiazole 
• 64-04-0 phenethylamine 
• 104-87-0 4-methyl-benzaldehyde 
• 106296-66-6 1-(benzothiazol-2-ylthio)-2-phenyl-1-(trimethylsilyl)ethane 

Downstream Products

• 95091-21-7 2-(phenethylsulfonyl)benzo[d]thiazole 
• 95091-08-0 sodium 2-phenylethane-1-sulfinate 
• 67399-12-6 (2-(benzylsulfonyl)ethyl)benzene 
• 95-16-9 1,3-Benzothiazole 
• 54798-95-7 2-butyl-benzothiazole 
• 4410-99-5 2-mercaptophenylethane 
• 14679-16-4 1-(1-butylthio)-2-phenylethane 

Relevant articles and documents

Ag-Cu copromoted direct C2-H bond thiolation of azoles with Bunte salts as sulfur sources

A direct C2-H thiolation of azoles with Bunte salts was achieved under the combined action of copper and silver salts. This protocol could furnish various substituted 2-thioazoles in moderate to good yields. This method has a broad substrate scope and shows good functional group tolerance.

Camphorquinone: A new and efficient oxidant for the preparation of 2-thio-substituted benzothiazoles from alcohols by oxidation-reduction condensation

A convenient one-pot procedure for the preparation of various 2-thio-substituted benzothiazoles from alcohols and benzothiazole-2-thiol utilizing camphorquinone-mediated oxidation-reduction condensation is disclosed. The condensation between benzothiazole-2-thiol and alkyl diphenylphosphinites, generated in situ from alcohols and chlorodiphenylphosphine, proceeded smoothly in the presence of camphorquinone to furnish the corresponding benzothiazoles in good to moderate yields.

Reactions of (Benzothiazol-2-ylthio)(trimethylsilyl)methane. A General Method for α-Mercaptoalkylation by Alkylation and Alkylative Desilylation

Readily available (benzothiazol-2-ylthio)(trimethylsilyl)methane (2a) provides a convenient synthon for HSCH2- and enables the general conversions RR'CO -> RR'C(OH)CH(SH)R'' and RBr -> RCH(SH)SiMe3.The lithium derivative of 2a reacts with aldehydes and ketones to give Peterson olefination products which are protected vinyl mercaptans converted into vinyl mercaptans by reaction with methyllithium.This overall conversion is RR'CO -> RR'C:CHSH.