934269-17-7Relevant articles and documents
One-pot multi-component synthesis and solid state structures of functionally rich polyether macrocycles
Vishe, Mahesh,Hrdina, Radim,Guenee, Laure,Besnard, Celine,Lacour, Jerome
supporting information, p. 3161 - 3169 (2013/12/04)
Densely functionalized polyether macrocycles can be prepared in one pot in yields up to 60% by the rhodium(II)-catalyzed decomposition of methyl diazoacetoacetate in the presence of a variety of substituted or unsaturated 5- and 6-membered ring cyclic ethers. A comprehensive analysis of the solid state conformations of the macrocyclic geometries is detailed as well as novel mechanistic insights about the multi-component condensation reaction. Copyright