935479-87-1

Basic information

• Product Name: 1,1-diisopropoxy-4-(4-nitro-phenyl)-but-3-en-2-one
• Synonyms: 1,1-diisopropoxy-4-(4-nitro-phenyl)-but-3-en-2-one
• CAS NO: 935479-87-1
• Molecular Weight: 307.346
• Mol File: 935479-87-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-diisopropoxy-4-(4-nitro-phenyl)-but-3-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-diisopropoxy-4-(4-nitro-phenyl)-but-3-en-2-one(935479-87-1)
• EPA Substance Registry System: 1,1-diisopropoxy-4-(4-nitro-phenyl)-but-3-en-2-one(935479-87-1)

Safety Data

• Hazardous Substances Data: 935479-87-1(Hazardous Substances Data)

Upstream product

• 59044-05-2 α,α-di(isopropoxy)acetone 
• 555-16-8 4-nitrobenzaldehdye 

Relevant articles and documents

Enantioselective cyanosilylation of α,α-dialkoxy ketones catalyzed by proline-derived in-situ-prepared N-oxide as bifunctional organocatalyst

Bifunctional N,N′-dioxide catalysts have been developed for highly enantioselective cyanosilylation of α,α-dialkoxy ketones. This process, catalyzed by in-situ-prepared proline-derived N,N′-dioxide 2b, produced the corresponding cyanohydrin trimethylsilyl ethers in excellent yields (up to 99%) with high enantioselectivities (up to 93% ee). A reasonable mechanism was proposed according to the observation of the linear effect, 1H NMR spectra, isolated cyanohydrin, and the roles of the NH and N-oxide moieties of the catalyst.