93625-20-8Relevant articles and documents
COMPETITIVE ADDITION OF GLYCOL DIFORMATE AND N-ETHYL-N-(2-FORMYLOXYETHYL) FORMAMIDE TO 1-HEXENE.
Germash,Zorin,Lapshova,Zlot-skii,Rakhmankulov
, p. 1104 - 1107 (2007/10/02)
For assessment of the reactivity of 2-substituted ethyl radicals, the authors studied competitive conversions of glycol diformate (I) and N-ethyl-N-(2-formyloxyethyl) formamide (II), initiated by tert-butyl peroxide, at 140 degree . It was found that conversion of equimolar amounts of glycol diformate (I) and N-ethyl-N-(2-formyloxyethyl) formamide (II) in presence of tert-butyl peroxide (III) at 140 degree results in parallel formation of ethyl formate (IV) and N,N-diethylformamide (V). Glycol diformate and N-ethyl-N-(2-formyloxyethyl) formamide add to 1-hexene in presence of tert-butyl peroxide to form octyl formate and N-ethyl-N-octylformamide respectively. 2-(N-Ethylformamido)ethyl radicals are less active than 2-formyloxyethyl in homolytic addition to 1-hexene.