93679-75-5Relevant articles and documents
The Identification of Azo Dyes. Part 3. Methylation of Sulphonate Groups and Mass Spectrometry
Sugiura, Takeo,Whiting, Mark C.
, p. 2426 - 2441 (2007/10/02)
Azo-dyes containing sulphonic acid groups can be extracted from water as tetrabutylammonium salts with methylene chloride, and converted by methyl fluorosulphate to methyl esters.These are sufficiently volatile and stable to give electron-impact mass spectra, in which molecular ions can usually be detected.Fragmentation patterns of authentic dye derivatives have been explored, to the point that identification of known dyes, and of unknown dyes related to known dyes, is usually straightforward, and in many cases the mass spectra of unseparated mixtures of azo dyes can be interpreted with assurance.The applications of dye identification to the dating of textiles and to the recognition of their country of origin, and thus (via assignment of textile to tribe) to the study of tribal migration, are summarised.