93788-48-8Relevant articles and documents
Six-Membered Cyclic Nitroso Acetals: Synthesis and Studies of the Nitrogen Inversion Process of N-Silyloxy-3,6-dihydro-2H-1,2-oxazines
Shved, Alexander S.,Tabolin, Andrey A.,Novikov, Roman A.,Nelyubina, Yulia V.,Timofeev, Vladimir P.,Ioffe, Sema L.
, p. 5569 - 5578 (2016)
Silyl nitronates undergo rhodium-catalyzed formal [3+3]-cycloaddition with enol diazoacetates to form N-silyloxy-3,6-dihydro-2H-1,2-oxazines. The scope of the reaction and the extent of the major side process were evaluated. A mechanistic scheme was propo
Functionalizing the γ-position of α-diazo-β-ketoesters
Nguyen, Thu Q.,Alqurafi, Maha,Edwards, Cash,Nguyen, Pauline,Kim, Jean,Casco, Samuel,Bennet, Maricka,Chiang, Christopher,Lohry, Maureen,Cox, Melina,Meshram, Byron,Le, Duyen,Kim, Eugene,Smriti, Snigdha,Oelschlaeger, Peter,Buynak, John D.
, p. 3330 - 3333 (2016/07/11)
Although α-diazo-β-ketoesters are synthetically versatile intermediates, methodology for introducing this functionality into complex molecules is still limited, most frequently involving a carboxylic acid precursor, which is then activated and transformed
A simple method of preparing trimethylsilyl- and tert-butyldimethylsilyl-enol eters of α-diazoacetoacetates and their use in the synthesis of a chiral precursor to thienamycin analogs
Ueda,Roberge,Vinet
, p. 2936 - 2940 (2007/10/02)
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