939-54-8 Usage
Description
2-Bromoethyl benzoate is an ester compound that consists of a benzoate group attached to a 2-bromoethyl moiety. It is characterized by its ability to participate in various chemical reactions due to the presence of the bromine atom, making it a versatile intermediate in organic synthesis.
Uses
Used in Chemical Synthesis:
2-Bromoethyl benzoate is used as a synthetic intermediate for the preparation of various organic compounds. Its reactivity arises from the bromine atom, which can be replaced by other functional groups through substitution reactions, allowing for the creation of a wide range of products.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 2-Bromoethyl benzoate is used as a building block for the synthesis of pharmaceutical agents. Its ability to undergo substitution reactions makes it a valuable component in the development of new drugs with specific therapeutic properties.
Used in Agrochemical Industry:
2-Bromoethyl benzoate is also utilized in the agrochemical industry for the synthesis of active ingredients in pesticides and herbicides. Its versatility in organic synthesis allows for the creation of compounds with targeted effects on pests and weeds, contributing to more effective and selective crop protection.
Used in Dye and Pigment Industry:
In the dye and pigment industry, 2-Bromoethyl benzoate serves as a key intermediate for the production of various dyes and pigments. Its chemical properties enable the synthesis of colorants with specific characteristics, such as brightness, stability, and solubility, which are essential for various applications in textiles, plastics, and printing inks.
Overall, 2-Bromoethyl benzoate is a valuable compound in the field of organic chemistry, with applications spanning across multiple industries due to its reactivity and potential for use in the synthesis of a diverse range of products.
Synthesis Reference(s)
The Journal of Organic Chemistry, 44, p. 3082, 1979 DOI: 10.1021/jo01331a027
Check Digit Verification of cas no
The CAS Registry Mumber 939-54-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,3 and 9 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 939-54:
(5*9)+(4*3)+(3*9)+(2*5)+(1*4)=98
98 % 10 = 8
So 939-54-8 is a valid CAS Registry Number.
InChI:InChI=1/C9H9BrO2/c10-6-5-7-3-1-2-4-8(7)9(11)12/h1-4H,5-6H2,(H,11,12)/p-1
939-54-8Relevant articles and documents
IrIII-Catalyzed direct syntheses of amides and esters using nitriles as acid equivalents: A photochemical pathway
Talukdar, Ranadeep
supporting information, p. 5303 - 5308 (2020/04/17)
An unprecedented IrIII[df(CF3)ppy]2(dtbbpy)PF6-catalyzed simple photochemical process for direct addition of amines and alcohols to the relatively less reactive nitrile triple bond is described herein. Various amides and esters are synthesized as the reaction products, with nitriles being the acid equivalents. A mini-library of different types of amides and esters is made using this mild and efficient process, which uses only 1 mol% of photocatalyst under visible light irradiation (λ = 445 nm). The reaction strategy is also efficient for gram-scale synthesis.
A study on reactions of an alkynylsilane with oxone-KX (X = Cl, Br, I) and its one-pot transformation into an amide/ester
Sriramoju, Vinodkumar,Jillella, Raveendra,Kurva, Srinivas,Madabhushi, Sridhar
, p. 560 - 562 (2017/03/30)
Oxyhalogenation reactions of a variety of alkynylsilanes were studied using oxone as mild oxidant and KCl, KBr, and KI as halogen sources. In this study, reaction of an alkynylsilane with oxone-KX (X = Cl or Br) produced trichloromethyl/tribromomethyl ketones inhigh yields. Under similar conditions, however, reactions of alkynylsilanes with oxone-KI were found to give exclusively 1,2,2-triiodovinyl derivatives in high yields. In this study, new methods were deveoped for effcient one-pot tranformation of alkynylsilanes into amides and esters by reaction with amines and alcohols respectively via trihalomethyl ketone.
Copper-catalyzed Csp3-O cross-coupling of unactivated alkyl halides with organic peroxides
Chen, Huan-Huan,Wang, Guang-Zu,Han, Jin,Xu, Meng-Yu,Zhao, Yong-Qiang,Xu, Hua-Jian
, p. 212 - 217 (2014/01/06)
An efficient Cu-catalyzed Csp3-O coupling of peroxides with haloalkanes is described. High yields of products were achieved under mild conditions. Significantly, in addition to primary alkyl halides, secondary alkyl halogenated hydrocarbons could also be applied to this system. The new reaction system could tolerate a wide range of organic peroxides.
