940-14-7

Basic information

• Product Name: (4-nitrophenyl)vinyl ether
• Synonyms: (4-nitrophenyl)vinyl ether;PARA-NITROPHENYLVINYLETHER
• CAS NO: 940-14-7
• Molecular Formula: C₈H₇NO₃
• Molecular Weight: 165.16
• Mol File: 940-14-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 261.9°Cat760mmHg
• Flash Point: 124.8°C
• Appearance: /
• Density: 1.206g/cm³
• Vapor Pressure: 0.0183mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: (4-nitrophenyl)vinyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (4-nitrophenyl)vinyl ether(940-14-7)
• EPA Substance Registry System: (4-nitrophenyl)vinyl ether(940-14-7)

Safety Data

• Hazardous Substances Data: 940-14-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H7NO3/c1-2-12-8-5-3-7(4-6-8)9(10)11/h2-6H,1H2

Upstream product

• 13288-06-7 1-(2-bromoethoxy)-4-nitrobenzene 
• 3383-72-0 1-(2-chloroethoxy)-4-nitrobenzene 
• 100-02-7 4-nitro-phenol 
• 106-93-4 ethylene dibromide 
• 108-05-4 vinyl acetate 
• 1112-56-7 tetravinyltin (IV) 
• 74-85-1 ethene 

Downstream Products

• 28042-94-6 4,4'-Dibutylthioazobenzol 
• 5679-91-4 4,4'-Bis-(butylthio)-azoxybenzol 
• 13595-00-1 4,4'-Dihydroxyazoxybenzol-divinylether 
• 19197-39-8 1,1-Bis-(p-nitrophenoxy)-aethan 
• 29037-95-4 2-methoxy-6-(4-nitro-phenoxy)-5,6-dihydro-[1,3,4]oxadiazine-4-carboxylic acid methyl ester 
• 1441-04-9 1,4,5,6,7,7-Hexachlor-2-<4-nitro-phenoxy>-bicyclo<2,2,1>hepten-(5) 
• 75269-50-0 2-phenyl-3-benzoyl-5-(p-nitrophenoxy)isoxazolidine 
• 111862-25-0 1-(1,2-Bis-thiocyanato-ethoxy)-4-nitro-benzene 
• 120166-39-4 C₁₄H₁₁BrClNO₃Se 
• 89249-66-1 3-Benzhydryl-5-(4-nitro-phenoxy)-4,5-dihydro-isoxazole 
• 59485-08-4 2-(4-nitrophenoxy)oxirane 
• 125708-05-6 2-Methoxy-2-(4-nitro-phenoxy)-ethanol 

Relevant articles and documents

Evaluation of 2-(piperidine-1-yl)-ethyl (PIP) as a protecting group for phenols: Stability to ortho-lithiation conditions and boiling concentrated hydrobromic acid, orthogonality with most common protecting group classes, and deprotection via Cope elimination or by mild Lewis acids

A new protecting group, 2-(piperidine-1-yl)-ethyl (PIP), was evaluated as a protecting group for phenols. The PIP group was stable to ortho-lithiation conditions and refluxing with concentrated hydrobromic acid. Deprotection was accomplished by two routes, oxidation to N-oxides followed by Cope elimination (CE) and subsequent hydrolysis or ozonolysis of the vinyl ether or one-step deprotection by BBr3?Me2S. The PIP group is orthogonal to the O-benzyl, O-acetyl, O-t-butyldiphenylsilyl, O-methyl, O-p-methoxybenzyl, O-allyl, O-tetrahydropyranyl and N-t-butoxy carbonyl groups. The CE step was systematically studied and was found to give higher yields when the reaction was performed in the presence of silylating agents.

Solid-Phase synthesis of aryl vinyl ethers based on polystyrenesupported aβ-phenylselenoethanol

A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported β-phenylselenoethanol with phenols under Mitsunobu conditions and subsequent oxidation-elimination with 30% hydrogen peroxide has been developed. The ad

Polymer-supported β-bromoethyl selenide: An efficient reagent for the synthesis of aryl vinyl ethers

A simple and efficient procedure for the solid-phase synthesis of aryl vinyl ethers using polymer-supported β-bromoethyl selenide with traceless linker strategy is described.